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  • CNC series (Cellulose Nanocrystals) or NCC series (Nanocrystalline Cellulose)

CNC series (Cellulose Nanocrystals) or NCC series (Nanocrystalline Cellulose)

Cellulose nanocrystals (CNC), also known as nanocrystalline cellulose (NCC), are derived from natural sources such as dissolving pulp, cotton, bleached kraft pulp (both softwood and hardwood), sisal, and tunicate cellulose. They are typically produced through acidic hydrolysis using acids like sulfuric, hydrochloric, phosphoric, or organic acids. The resulting CNC can appear as a suspension or powder, exhibiting blue or brown hues.

CNC particles vary in size depending on their source:

  • Pulp or Cotton-Derived CNC: Width ranges from 10 to 20 nanometers (nm), with lengths between 50 and 400 nm.
  • Tunicate-Derived CNC: Width remains between 10 to 20 nm, but lengths extend from 500 nm up to 2 micrometers (μm), resulting in an aspect ratio of approximately 75.

These nanocrystals boast a crystallinity index exceeding 70%, indicating a high degree of structural order. In suspension form, CNCs resist hard agglomeration and can be redispersed in water after drying, especially with ultrasonic treatment. Notably, CNCs modified through organic acid hydrolysis (CNC-OA) can disperse in organic solvents. The solid content of CNC suspensions typically ranges from 0.5% to 10%.

Chemical modifications, including anionization, cationization, carboxymethylation, and polymer grafting, can be applied to CNCs to tailor their properties for specific applications. These versatile nanomaterials hold promise across various industries, from environmental remediation and engineering to pharmaceuticals and biodegradable packaging. Their potential to replace petrochemical-based products offers a sustainable and cost-effective alternative in the realm of high-performance nanomaterials.

Catalog Number


Product

Fiber dimensions, Surface group

Form


RN-CL-CNC-Slurry-Regular

Cellulose Nanocrystals, Sulfuric acid hydrolysis

Width: 5-20 nm;
Length: 100-250 nm
Surface Group: Hydroxyl, sulfonic group,
Hydrophilic

0.5 - 6% solids in water

RN-CL-CNC-Slurry-HS

Cellulose Nanocrystals, Sulfuric acid hydrolysis, high sulfonic group content

Width: 5-20 nm;
Length: 100-250 nm
Surface Group: Hydroxyl, sulfonic group,
Hydrophilic

0.5 - 10% solids in water

RN-CL-CNC-Slurry-DS

Cellulose Nanocrystals, Desulfated

Width: 5-20 nm;
Length: 140-200 nm
Surface Group: Hydroxyl
Hydrophilic

0.5% - 8% in water

RN-CL-CNC-Slurry-CM

Carboxymethylated Cellulose Nanocrystals, Pulp material

Width: 5-20 nm;
Length: 140-200 nm
Surface Group: carboxymethyl group, hydroxyl
Hydrophilic

0.5% - 5%

RN-CL-CNC-Anionic-Low

Cellulose Nanocrystals , Anionic type, carboxyl group content (0.15 - 0.4 mmol/g); Ordered upon request

Width: 5-20 nm;
Length: 140-200 nm
Surface Group: Carboxyl group, hydroxyl
Hydrophilic

0.5% - 2% in water

RN-CL-CNC-Anionic-Medium

Cellulose Nanocrystals , Anionic type, carboxyl group content (0.8 - 1.2 mmol/g); Ordered upon request

Width: 5-20 nm;
Length: 140-200 nm
Surface Group: Carboxyl group, hydroxyl
Hydrophilic

0.5% - 2% in water

RN-CL-CNC-Anionic-High

Cellulose Nanocrystals , Anionic type, carboxyl group content ( >1.5 mmol/g); Ordered upon request

Width: 5-20 nm;
Length: 140-200 nm
Surface Group: Carboxyl group, hydroxyl
Hydrophilic

0.5% - 2% in water

RN-CL-CNC-Cationic

Cationic type Cellulose Nanocrystals; Ordered upon request

Width: 5-20 nm;
Length: 140-200 nm
Surface Group: Quaternary ammonium, hydroxyl
Hydrophilic

0.5% - 2% in water

RN-CL-CNC-Tunicate

Tunicate Cellulose Nanocrystals, marine biomass with high aspect ratio, sulfuric acid hydrolysis; Ordered upon request

Width: 5-20 nm;
Length: 500 nm -2 um
Surface Group: Hydroxyl, sulfonic group,
Hydrophilic

0.5 - 2% solids in water

RN-CL-CNC-FA-Regular

Cellulose Nanocrystals, Formic acid hydrolysis; Substitution degree < 0.5; Ordered upon request

Width:5-30 nm;
Length:50-300nm
Surface Group: Ester, hydroxyl
Hydrophobic

Precipitated slurry in water

RN-CL-CNC-FA-High

Cellulose Nanocrystals, Formic acid hydrolysis; High Substitution Degree (SD around 1.1); Ordered upon request

Width:5-30 nm;
Length:50-300nm
Surface Group: Ester, hydroxyl
Hydrophobic

Precipitated slurry in water

RN-CL-CNC-PA

Cellulose Nanocrystals, Phosphoric acid hydrolysis; Ordered upon request

Width:5-30 nm;
Length:50-300nm
Surface Group: Phosphate, hydroxyl
Hydrophilic

0.5 - 1% in water

RN-CL-CNC-EP

Cellulose Nanocrystals, epoxy grafted; Ordered upon request

Width: 5-20 nm;
Length: 140-200 nm
Surface Group: Epoxy, hydroxyl group
Hydrophilic

1% - 5% in water

RN-CL-CNC-Hydrophobic

Cellulose Nanocrystals, Hydrophobic; Ordered upon request

Width: less than 100 nm;
Length: less than 100 nm
Surface Group: Ester group, hydroxyl
Hydrophobic

Dry powder

RN-CL-CNC-SD

Cellulose Nanocrystals Spray‐dried

Width: 5-20 nm;
Length: 140-200 nm
Surface Group: Hydroxyl, sulfonic group
Hydrophilic

Dry powder

RN-CL-CNC-FD

Cellulose Nanocrystals Freeze‐dried

Width: 5-20 nm;
Length: 100-250 nm
Surface Group: Hydroxyl, sulfonic group
Hydrophilic

Dry powder

RN-CL-CNC-HS-SD

Cellulose Nanocrystals, high sulfonic group content, Spray‐dried

Width: 5-20 nm;
Length: 140-200 nm
Surface Group: Hydroxyl, sulfonic group
Hydrophilic

Dry powder

RN-CL-CNC-HS-FD

Cellulose Nanocrystals, high sulfonic group content, Freeze‐dried

Width: 5-20 nm;
Length: 100-250 nm
Surface Group: Hydroxyl, sulfonic group
Hydrophilic

Dry powder

RN-CL-CNC-DS-SD

Cellulose Nanocrystals, Desulfated, Spray-dried powder

Width: 5-20 nm;
Length: 140-200 nm
Surface Group: Hydroxyl
Hydrophilic

Dry powder

RN-CL-CNC-DS-FD

Cellulose Nanocrystals, Desulfated, Freeze-dried powder

Width: 5-20 nm;
Length: 140-200 nm
Surface Group: Hydroxyl
Hydrophilic

Dry powder

RN-CL-CNC-CM-SD

Carboxymethylated Cellulose Nanocrystals, Spray-dried, Pulp material

Width: 5-20 nm;
Length: 140-200 nm
Surface Group: carboxymethyl group, hydroxyl
Hydrophilic

Dry powder

RN-CL-CNC-Cationic-FD

Cationic type Cellulose Nanocrystals; Freeze-dried powder, Ordered upon request

Width: 5-20 nm;
Length: 140-200 nm
Surface Group: Quaternary ammonium, hydroxyl
Hydrophilic

Dry powder

RN-CL-CNC-Anionic-FD

Cellulose Nanocrystals, Anionic type, carboxyl group content ( >=1.5 mmol/g); Ordered upon request

Width: 5-20 nm;
Length: 140-200 nm
Surface Group: Carboxyl group, hydroxyl
Hydrophilic

Dry powder

RN-CL-CNC-FA-Regular-FD

Cellulose Nanocrystals, Formic acid hydrolysis; Substitution degree < 0.5; Freeze-dried powder, Ordered upon request

Width:5-30 nm;
Length:50-300nm
Surface Group: Ester, hydroxyl
Hydrophobic

Dry powder

RN-CL-CNC-FA-High-FD

Cellulose Nanocrystals, Formic acid hydrolysis; High Substitution Degree (SD around 1.1); Freeze-dried powder, Ordered upon request

Width:5-30 nm;
Length:50-300nm
Surface Group: Ester, hydroxyl
Hydrophobic

Dry powder

RN-CL-CNC-Aerogel

Cellulose Nanocrystal Aerogel (liquid nitrogen process); Hydrophilic; Ordered upon request; Contact us for aerogel density and size info

Width: 5-20 nm;
Length: 100-250 nm
Surface Group: Hydroxyl, sulfonic group,
Hydrophilic

Aerogel

Below is a table summarizing the key characteristics of CNCs:

AttributeDetails
Source MaterialsDissolving pulp, cotton, bleached kraft pulp (softwood and hardwood), sisal, tunicate cellulose
Production MethodAcidic hydrolysis using sulfuric, hydrochloric, phosphoric, or organic acids
AppearanceSuspension or powder; blue or brown color
Particle Dimensions- Pulp/Cotton CNC: 10–20 nm width, 50–400 nm length
- Tunicate CNC: 10–20 nm width, 500 nm to 2 μm length (aspect ratio ~75)
Crystallinity Index>70%
Dispersion Properties- CNC suspensions resist hard agglomeration and can be redispersed in water post-drying with ultrasonic treatment
- CNC-OA disperses in organic solvents
Solid Content0.5% to 10%
Chemical ModificationsAnionization, cationization, carboxymethylation, polymer grafting
ApplicationsEnvironmental remediation, engineering, pharmaceuticals, biodegradable packaging; potential replacement for petrochemical-based products due to sustainability and cost-effectiveness in high-performance nanomaterials


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